The difference between "arrive in" and "arrive at" is based on the type of place you're referring to.
Arrive in
"Arrive in" is used for larger geographical areas like countries and cities.
They will arrive in the city soon.
We arrived in New York last night.
She arrived in France for her vacation.
She arrived in the village just before sunset.
She arrived in the small town by the coast.
When do you think you’ll arrive in the capital?
The team arrived in Africa for the wildlife expedition.
We finally arrived in the countryside after a long drive.
Arrive at
"Arrive at" is used for specific points or smaller locations like buildings or events.
He arrived at the airport on time.
We arrived at the train station early.
They arrived at the hotel late last night.
She arrived at the office early this morning.
We arrived at the university for the lecture.
We arrived at the town square just before noon.
Island
When using "arrive" with "island," both "arrive in" and "arrive at" can be correct depending on the context and whether you view the island as a general area (larger region) or a specific point (small location).
We arrived in Hawaii after a long flight.
I’ll arrive at the island by ferry in the afternoon.
We arrived in Fiji (large island group), but we stayed at a smaller private island.
In summary
We arrived in London. (a large city)
We arrived at the London Eye. (a specific location within the city)
He arrived in Italy, then took a taxi and arrived at the hotel.
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